Compression Comparison
In a word, NO. Compression ratio is based on squeezing the swept area into the unswept area of the cylinder. Compression ratio is figured on the gross combustion area in the cylinder,when the piston is at bottom dead center, divided by the unswept area, which is the area above the top of the piston when its at top dead center. This gives you the static compression ratio.
Cylinder PSI is the actual pressure built in the cylinder, when the mixture is totally compressed.
There are a lot of factors governing PSI, cam overlap, cam timing, are two major factors.
For example; a 64 289 2 bbl engine with 9:1 compression, spec'd at 150 PSI.
A 64 260 2 bbl engine with 8.7:1 spec'd at 150 PSI, and a 200 cube 6, with 8.7:1 compression spec'd at 170 PSI.