First of all we need to know what you are working on. A Chevy? A Briggs & Stratton lawn mower? A Ferrari?
If you are assembling a stock engine, with stock head bolts, it is time you got a factory service manual. Not only will it tell you what lubricant to use, it will tell you the torque value, and the sequence you tighten the bolts in. You might also have an engine that requires the intake manifold, or other parts to be to be installed before completing the head bolt tightening process. The manual will also tell you if you can reuse the head bolts. On some engines, you do not reuse head bolts.
If you are using aftermarket bolts, follow the directions that came with them.
But before you start, you need to get a bottoming tap, and chase the threads in the block, to clean them out. If you are reusing the stock bolts, clean the threads on them, also.