You NEED to block them or
want to block them? If you drive in cold weather you might want to reconsider this and just block one side.
I have used two pieces (one for each side of the engine) of 0.035" stainless steel shim stock cut to size and slid in between the heads and intake gaskets and drove it like that for 50K miles until it was sold. Pontiac 455 w/ a Performer intake, driven in central FL year 'round. Mild (strongly magnetic) steel won't last as long.
Furnace cement is a lot better than molten aluminum IMHO. It requires a heat cure, so the heads need to go into the oven for a while. The cement expands some so you don't need to allow it to come all the way out of the port like shown on one of my heads below. A 1 to 1-1/2" plug made from this cement, placed 1/2" inside the crossover will do nicely.