Depends on a lot of the subtle features of the chamber. Generally smaller chambers pull the spark plug in toward the center of the chamber. This reduces burn time as the flame front radiates in all directions compared to larger chambers where the spark plug is located to the side causing a longer burn time because the flame front has to travel side to side. This is not always true for aftermarket chambers which often push the spark plug toward the center. This is something you have to look for, never buy a head that you haven't seen the chamber. The older smog heads and some, but not all, stock replacement heads from the aftermarket are large 74-76 cc chambers with the plug located far to the outside of the chamber. Aftermarket, GMPP, and certainly as you get into the late 1980's to mid 1990's production feature chambers that are smaller 58 (aluminum L98), 64, 66 ccs that are approaching the shape but are not exactly like the 1996 L31 Vortec head. You also have to be careful of the mid 80's through mid 90's Swirl Port head this uses the better chambers of that era in both 64 and 76 ccs with the more centered spark plug but fill half the valve pocket with a flow restricting swirl vane. These make great torque and get excellent fuel mileage but cannot make much power as RPMs are restricted to about 4000 max before the port chokes off.
The L31 Vortec was a game changer with improved intake porting and full Ricardo chambers where the volume is small at 64 ccs with the spark plug pushed inward as much as the valve location allows. The intake side of the chamber is shaped with an eye to generating swirl without a vane and mixing the wet flow into the air stream. The squish/quench side of the chamber features a beak that extendeds between the inlet and exhaust valve to redirect the secondary intake flow away from the exhaust valve so fresh mixture is not lost out the exhaust during valve overlap. This reduces emissions and improves cylinder filling resulting in greater power and improved fuel mileage.
This type chanber has been incorporated by all the OEMs and the aftermarket. Some are better laid out than others but all are quite to very good.
For the hot rodder the aftermarket piston companies came up with the D shaped dish, sometimes called the cup, that resides under the valve pocket. The volume of the dish/cup is used along with the volume of the combustion chamber and other clearances to establish the static compression ratio. The factories still can't bring themselves to ditch the round dish. The advantage of the D dish is it allows a larger area of the piston crown to be flat and close closely under the heads squish/quench step as found with a flat top piston. This maximizes the effects of squish that performs a final mix of the fuel and air; then pushes the mixture across the chamber into the valve pocket before the spark plug. This makes it easy for the spark to fire and the high density of the mixture burns quickly reducing the need for large amounts of spark lead which better aligns the period of maximum cylinder pressure with the piston/crankshaft angles most suited to extract the power from that combustion pressure and place it into the crankshaft. Following the initial burn; the quench or heat sink of the farside of the chamber having a lot of surface area and not a lot of volume prevents remaining mixture from self igniting before the flame front gets there. This provides a high amount of detonation resistance (called mechanical octane) which makes the octane of the fuel used appear higher than its rating.
The intake porting of the L31 vortec is unique and took a different direction than classic ot rod porting. First the roof was raised which is classic hot rod porting to raise the roof and widen the port alongside the guide toward the bore wall side of the port where the major flow is. GM pretty much left this alone but widened the floor which leads to the tight bottom turn into the pocket. Widening this would slow the flow velocity in this area which would help keep the flow attached to the floor as it makes the turn into the pocket which should increase this secondary flow onto the back side of the valve. This works extremely well for lifts not over .5 inch which are typical for factory cams. For hot rod max performance with lifts higher than .5 inch the port is opened up in the more conventonal manner. The aftermarket does a lot of mixing of port shapes and locations with the Vortec style chamber, some heads will only accept the raised port and unique bolt patterned intake, others use the older port sizes and locations along with the earlier bolt pattern and still others accept either intake.
So you've got lots of, if not too many choices, I'm sure we'd be happy to comment on your selections if you care to hear.
Bogie